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Softening
water Magic Realism |
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"The
Economist" March 2, 1996 issue. Arthur C. Clarke once famously pronounced that any sufficiently
advanced technology is indistinguishable from magic. The reverse, of
course, is not so true. Just because something seems to need magic to
explain it does not make it an advanced technology: a more conventional
explanation, such as sleight of hand, is usually involved. Even so, some apparently magical
ideas survive even when there is no decent scientific explanation for
them. One is that applying a magnetic field to a water pipe can soften the
water flowing through it and so prevent the pipe from scaling up.
Devices based on this idea crop up regularly in the classified
advertisements, alongside improved potato-peelers and better mousetraps.
Domestic versions cost around $300; industrial ones up to $30,000. Physicists,
unable to explain how such machines could work, have dismissed them for
years. Physicists, it appears, are wrong. The evidence comes from Simon Parsons and his team at Cranfield
University in Britain. They put the tale to the test and found that it is
not as tall as it seems. Indeed, given the right combination of magnetism,
temperature, acidity and water flow, they found that the rate of scaling
could be halved. This is potentially impressive. Dr. Parsons reckons that
scaling costs British industry $1.5 billion a year. Halving that cost
would be a useful gain. What is not clear is just how the process works.
On March 14th a seminar at Cranfield, which will be addressed by
physicists from America and Japan, as well as Europe, will explore the
problem. One clue they will have to go on is that the limited amounts of
scale produced in Dr. Parson's experiments do not form a solid crust that
requires major surgery to remove, but rather a powdery layer that can be
eliminated with a stiff brushing. Examined under an electron microscope,
the crystals that make up this layer look circular. Those in common or
garden lime scale are rectangular. It seems that the magnetic field
changes the way in which the calcium carbonate that makes up scale
crystallizes. Dr. Parson sees four possible explanations. The most esoteric is
that the magnetic field is changing the shape of the orbitals occupied by
the electrons surrounding the atoms involved. This would certainly change
their chemical reactivity. But he thinks it is extremely unlikely that his
magnets could have this effect. Another possibility is that the field is causing impurities in the
water, such as iron atoms, to stick together in ways that form nucleation
sites: places around which calcium carbonate can easily crystallize. By
forming in the flowing water, rather than accumulating on the edge of the
pipe, the crystals would not fur things up. The third idea is that the magnetism changes the way that calcium
ions attract water molecules. When ions (electrically charged atoms)
dissolve in water, their charges cause nearby water molecules to cluster
around them. This, of course, interferes with their ability to react with
other ions. If you make changes in the nature of its protective shell, you
change an ion's reactivity. The fourth theory is that the field distorts the electrical charge
that is carried by small particles of calcium carbonate that have already
formed in the water. This, in turn, affects the way they stick together to
form large particles. For Dr. Parson's money, the fourth explanation is the most likely.
It is the only one that fits with the observation that the magnets work
only on flowing water. Whereas electrically charged objects sitting still
in a magnetic field do nothing, those moving through a field generate a
further electrical charge, which will also change their attractiveness to
each other. Dr. Parson's money, though, is not the only interested cash. The oil
industry, in particular, is watching the work done at Cranfield. Oil wells
face major scaling problems from the highly mineralized waters extracted
along with the pay dirt. Chemical treatment costs as much as $750,000 a
year for a typical North Sea platform, and some magnetic devices are
already being tested; an industry that is often based on hunches is
certainly willing to give them a try. But without a theoretical
explanation for the magic boxes, which would give some idea of their
limitations, hard-headed engineers are reluctant to invest in them more
widely. Perhaps, if Dr. Parsons and his collaborators can manage to
explain this particular magic, a new technology will be born. (Note: Dollar amounts have been changed from British Pounds to US
Dollars)
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